Articles | Volume 13, issue 3
https://doi.org/10.5194/os-13-427-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/os-13-427-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
24 May 2017
Research article |
| 24 May 2017
Measuring pH variability using an experimental sensor on an underwater glider
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK
Laboratoire d'Océanographie et du Climat, 4 Place Jussieu, 75005 Paris, France
Jan Kaiser
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK
Karen J. Heywood
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK
Dorothee C.E. Bakker
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK
Jacqueline Boutin
Laboratoire d'Océanographie et du Climat, 4 Place Jussieu, 75005 Paris, France
Kiminori Shitashima
Tokyo University of Marine Science and Technology, 4-5-7 Konan, Minato, Tokyo 108-0075, Japan
Gareth Lee
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK
Oliver Legge
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ, UK
Reiner Onken
Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
Related authors
No articles found.
Marta Stentella, Ghislain Picard, Petra Heil, Jacqueline Boutin, Emmanuel Dinnat, and Stuart Corney
The Cryosphere, 20, 4465–4489, https://doi.org/10.5194/tc-20-4465-2026, https://doi.org/10.5194/tc-20-4465-2026, 2026
Short summary
Short summary
Passive microwave radiometers are the primary tool for monitoring Antarctic sea ice, but their reliability decreases in the marginal ice zone between the pack ice and the open ocean. We simulate satellite observations to assess the impact of varying physical parameters on sea ice concentration retrievals. The largest errors are due to flooded/wet snow, thin ice, and roughened ocean surfaces. These findings can improve our interpretation of satellite observations and forecast sea ice changes.
Robert J. W. Brewin, Bethany Wilkinson, Xuerong Sun, Giorgio Dall'Olmo, Gavin H. Tilstone, Katharine R. Hendry, Sarah Breimann, Ian Brown, Angus Atkinson, Katrin Schmidt, Elisabetta Canuti, Meredith G. Meyer, Qi Zheng, Johannes J. Viljoen, Tom Bell, and Karen J. Heywood
EGUsphere, https://doi.org/10.5194/egusphere-2026-4398, https://doi.org/10.5194/egusphere-2026-4398, 2026
This preprint is open for discussion and under review for Ocean Science (OS).
Short summary
Short summary
Phytoplankton are the foundation of the Antarctic food web. Their size affects carbon storage in the ocean and energy transfer to krill, fish, and whales. Because the northwestern Weddell Sea is rarely sampled, little is known about phytoplankton size there. Using ship-based measurements and satellite data, we found medium-sized phytoplankton dominate rather than the smallest types that dominate warmer oceans. This provides a baseline for tracking ecosystem responses to climate change.
Enzo Forestier, Luther Ollier, Roy El Hourany, Jacqueline Boutin, Carlos Mejia, and Sylvie Thiria
Ocean Sci., 22, 2357–2373, https://doi.org/10.5194/os-22-2357-2026, https://doi.org/10.5194/os-22-2357-2026, 2026
Short summary
Short summary
This study evaluates deep generative diffusion models for downscaling sea surface salinity in the Gulf Stream. Using a reanalysis dataset as a controlled framework, it assesses the added value of high-resolution sea surface temperature and sea surface height as auxiliary constraints. The results show that diffusion-based reconstructions preserve plausible fine-scale variability, highlighting the method’s potential for future applications to satellite products.
Hendrik Fuchs, Niklas Illmann, Amalia Muñoz, Mila Ródenas, Bénédicte Picquet-Varrault, M. Rami Alfarra, Cecilia Arsene, Iustinian G. Bejan, David M. Bell, Merete Bilde, Alexander Böhmländer, Mixtli Campos-Pineda, Mathieu Cazaunau, Patrice Coll, Véronique Daële, Claudia Di Biagio, Michael Flynn, Paola Formenti, Hartmut Herrmann, Kristina Höhler, Thorsten Hohaus, Matthew S. Johnson, Eija Juurola, Niku Kivekäs, Jan Kaiser, Christos Kaltsonoudis, Paolo Laj, Dario Massabò, Federico Mazzei, Gordon McFiggans, Max R. McGillen, Abdelwahid Mellouki, Peter Mettke, Ottmar Möhler, Falk Mothes, Dennis Niedermeier, Anna Novelli, Romeo I. Olariu, Spyros N. Pandis, Iulia Patroescu-Klotz, Rosa Maria Petracca Altieri, Paolo Prati, Claudiu Roman, Albert A. Ruth, Harald Saathoff, Silvio Schmalfuß, Frank Stratmann, Virginia Vernocchi, Aristeidis Voliotis, Jens Voigtländer, Annele Virtanen, Andreas Wahner, Robert Wagner, John Wenger, Sören Zorn, Peter Wiesen, and Jean-Francois Doussin
Atmos. Meas. Tech., 19, 4165–4199, https://doi.org/10.5194/amt-19-4165-2026, https://doi.org/10.5194/amt-19-4165-2026, 2026
Short summary
Short summary
Atmospheric simulation chambers enable experiments to be conducted under controlled conditions, improving our understanding of, and ability to predict, changes in the composition of the atmosphere. This is important for assessing air quality and its effects on human health, climate, the environment, and the economy. This paper describes the chambers of the European ACTRIS research infrastructure and discusses topics and directions that can be addressed in future chamber experiments.
Meredith G. Meyer, Robert J. W. Brewin, Xuerong Sun, Clara Manno, Florence Atherden, Sasha J. Kramer, Giorgio Dall'Olmo, and Karen J. Heywood
EGUsphere, https://doi.org/10.5194/egusphere-2026-3148, https://doi.org/10.5194/egusphere-2026-3148, 2026
Short summary
Short summary
Antarctica is a key region for carbon cycling and export. The efficiency of carbon export has been linked to the type of phytoplankton dominating the system. Our results suggest diatoms, haptophytes, and cryptophytes are present in all water column samples despite substantial physical differences between sampling locations. Our data shows a strong relationship between the proportion of diatoms, haptophytes, and cryptophytes relative to all other phytoplankton and the magnitude of carbon flux.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Kjetil Aas, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Nicolas Bellouin, Alice Benoit-Cattin, Carla F. Berghoff, Raffaele Bernardello, Laurent Bopp, Ida Bagus Mandhara Brasika, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Nathan O. Collier, Thomas H. Colligan, Margot Cronin, Laique M. Djeutchouang, Xinyu Dou, Matt P. Enright, Kazutaka Enyo, Michael Erb, Wiley Evans, Richard A. Feely, Liang Feng, Daniel J. Ford, Adrianna Foster, Filippa Fransner, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Jefferson Goncalves De Souza, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Bertrand Guenet, Özgür Gürses, Kirsty Harrington, Ian Harris, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Akihiko Ito, Andrew R. Jacobson, Atul K. Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Steve D. Jones, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Yawen Kong, Jan Ivar Korsbakken, Charles Koven, Taro Kunimitsu, Xin Lan, Junjie Liu, Zhiqiang Liu, Zhu Liu, Claire Lo Monaco, Lei Ma, Gregg Marland, Patrick C. McGuire, Galen A. McKinley, Joe R. Melton, Natalie Monacci, Erwan Monier, Eric J. Morgan, David R. Munro, Jens D. Müller, Shin-Ichiro Nakaoka, Lorna R. Nayagam, Yosuke Niwa, Tobias Nutzel, Are Olsen, Abdirahman M. Omar, Naiqing Pan, Sudhanshu Pandey, Denis Pierrot, Zhangcai Qin, Pierre Regnier, Gregor Rehder, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, Ingunn Skjelvan, T. Luke Smallman, Victoria Spada, Mohanan G. Sreeush, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Didier Swingedouw, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Xiangjun Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Erik van Ooijen, Guido R. van der Werf, Sebastiaan J. van de Velde, Anthony P. Walker, Rik Wanninkhof, Xiaojuan Yang, Wenping Yuan, Xu Yue, and Jiye Zeng
Earth Syst. Sci. Data, 18, 3211–3288, https://doi.org/10.5194/essd-18-3211-2026, https://doi.org/10.5194/essd-18-3211-2026, 2026
Short summary
Short summary
The Global Carbon Budget 2025 describes the methodology, main results, and datasets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2025). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Luke Gregor, Alizée Roobaert, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kunal Chakraborty, Ana C. Franco, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Prasanna Kanti Ghoshal, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Debby Ianson, Yosuke Iida, Masao Ishii, Apurva Padamnabh Joshi, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Liang Xue, Hyelim Yoo, Jiye Zeng, and Guorong Zhong
Earth Syst. Sci. Data, 18, 1405–1462, https://doi.org/10.5194/essd-18-1405-2026, https://doi.org/10.5194/essd-18-1405-2026, 2026
Short summary
Short summary
This review article provides an overview of 68 existing ocean carbonate chemistry data products and data product sets, encompassing a broad range of types, including compilations of cruise datasets, gap-filled observational products, model simulations, and more. It is designed to help researchers identify and access the data products that best support their scientific objectives, thereby facilitating progress in understanding the ocean's changing carbonate chemistry.
Tom A. Jordan, Karen J. Heywood, Anna Wåhlin, Rob A. Hall, Atsuhiro Muto, Pierre Dutrieux, Kelly Hogan, James Girton, Karen E. Alley, and Erin Pettit
EGUsphere, https://doi.org/10.5194/egusphere-2025-6001, https://doi.org/10.5194/egusphere-2025-6001, 2026
Short summary
Short summary
The shape of the water filled cavity hidden beneath ice shelves is extremely important, but hard to measure. Gravity data collected from aircraft can be used to predict the shape. However, in the Dotson Crosson ice shelves in West Antarctica, new direct observations from autonomous platforms sent beneath the ice, and seismic observations from the ice surface showed gravity models were systematically too shallow. We explain why and provide a solution applicable her and in other ice shelves.
Maren Elisabeth Richter, Karen J. Heywood, Rob A. Hall, and Peter E. D. Davis
Ocean Sci., 21, 3341–3359, https://doi.org/10.5194/os-21-3341-2025, https://doi.org/10.5194/os-21-3341-2025, 2025
Short summary
Short summary
Warm ocean water causes rapid melting of Antarctic glaciers. The circulation and mixing of warm water in ice shelf cavities is mostly unknown. We observed ocean currents and mixing under Dotson Ice Shelf. Mixing is low, with patches of higher mixing associated with stronger currents and vertical current shear. The levels of turbulent mixing will lead to negligible heat loss during the path of the warm water to the grounding line, leaving plenty of heat available to melt the ice shelf there.
Daisy D. Pickup, Dorothee C. E. Bakker, Karen J. Heywood, Francis Glassup, Emily M. Hammermeister, Sharon E. Stammerjohn, Gareth A. Lee, Socratis Loucaides, Bastien Y. Queste, Benjamin G. M. Webber, and Patricia L. Yager
Ocean Sci., 21, 2727–2741, https://doi.org/10.5194/os-21-2727-2025, https://doi.org/10.5194/os-21-2727-2025, 2025
Short summary
Short summary
Autonomous platforms in the Amundsen Sea have allowed for detection of isolated water masses that are colder, saltier and denser than overlying water. They are also associated with a higher dissolved inorganic carbon concentration and lower pH. The water masses, referred to as lenses, could have implications for the transfer of heat and storage of carbon in the region. We hypothesise that they form in surrounding areas that experience intense cooling and sea ice formation in autumn/winter.
Christian T. Wild, Tasha Snow, Tiago S. Dotto, Peter E. D. Davis, Scott Tyler, Ted A. Scambos, Erin C. Pettit, and Karen J. Heywood
Ocean Sci., 21, 2605–2629, https://doi.org/10.5194/os-21-2605-2025, https://doi.org/10.5194/os-21-2605-2025, 2025
Short summary
Short summary
Thwaites Glacier is retreating due to warm ocean water melting it from below, but its thick ice shelf makes this heat hard to monitor. Using hot-water drilling, we placed sensors beneath the floating ice, revealing how surface freezing in Pine Island Bay influences heat at depth. Alongside gradual warming, we found bursts of heat that could speed up melting at the grounding zone, which may become more common as sea ice declines.
Shenjie Zhou, Pierre Dutrieux, Claudia F. Giulivi, Adrian Jenkins, Alessandro Silvano, Christopher Auckland, E. Povl Abrahamsen, Michael Meredith, Irena Vaňková, Keith Nicholls, Peter E. D. Davis, Svein Østerhus, Arnold L. Gordon, Christopher J. Zappa, Tiago S. Dotto, Ted Scambos, Kathryn L. Gunn, Stephen R. Rintoul, Shigeru Aoki, Craig Stevens, Chengyan Liu, Sukyoung Yun, Tae-Wan Kim, Won Sang Lee, Markus Janout, Tore Hattermann, Julius Lauber, Elin Darelius, Anna Wåhlin, Leo Middleton, Pasquale Castagno, Giorgio Budillon, Karen J. Heywood, Jennifer Graham, Stephen Dye, Daisuke Hirano, and Una Kim Miller
Earth Syst. Sci. Data, 17, 5693–5706, https://doi.org/10.5194/essd-17-5693-2025, https://doi.org/10.5194/essd-17-5693-2025, 2025
Short summary
Short summary
We created the first standardised dataset of in-situ ocean measurements time series from around Antarctica collected since 1970s. This includes temperature, salinity, pressure, and currents recorded by instruments deployed in icy, challenging conditions. Our analysis highlights the dominance of tidal currents and separates these from other patterns to study regional energy distribution. This unique dataset offers a foundation for future research on Antarctic ocean dynamics and ice interactions.
Ana Claudia Parracho, Patricia Zunino, Michela Sammartino, Jacqueline Boutin, Eric Greiner, Bruno Buongiorno Nardelli, and Nicolas Kolodziejczyk
State Planet Discuss., https://doi.org/10.5194/sp-2025-3, https://doi.org/10.5194/sp-2025-3, 2025
Revised manuscript accepted for SP
Short summary
Short summary
We compared six global sea surface salinity datasets and found consistent trends between them. Many regions follow the known pattern of fresh areas getting fresher and salty areas saltier, with a growing contrast between the North Atlantic and North Pacific. However, comparison with longer-term data shows that short-term trends are strongly shaped by natural climate variability, especially in the Pacific.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Christopher Hunt, Thomas Linkowski, Alison Chase, Nils Haentjens, Pedro C. Junger, Stéphane Pesant, and Douglas Vandemark
Earth Syst. Sci. Data, 17, 3583–3598, https://doi.org/10.5194/essd-17-3583-2025, https://doi.org/10.5194/essd-17-3583-2025, 2025
Short summary
Short summary
The air–sea CO2 flux in coastal waters plays a key role in the global carbon budget but remains poorly understood. In 2021, the Tara schooner collected 14 000 km of CO2 fugacity (fCO2) data along the South American coast. This dataset improves our understanding of fCO2 in the under-sampled Brazilian coastal region and provides a unique insight into the complex biogeochemistry of the Amazon River–ocean continuum.
Meredith G. Meyer, Esther Portela, Walker O. Smith Jr., and Karen J. Heywood
Ocean Sci., 21, 1223–1236, https://doi.org/10.5194/os-21-1223-2025, https://doi.org/10.5194/os-21-1223-2025, 2025
Short summary
Short summary
During the annual phytoplankton bloom, rates of primary production and carbon export in the Ross Sea, Antarctica, are uncoupled from each other and from oxygen and carbon stocks. These biogeochemical rates support the high-productivity, low-export classification of the region and suggest that environmental factors influence these stocks and rates differently and make projections under future climate change scenarios difficult.
Kirtana Naëck, Jacqueline Boutin, Sebastiaan Swart, Marcel du Plessis, Liliane Merlivat, Laurence Beaumont, Antonio Lourenco, Francesco d'Ovidio, Louise Rousselet, Brian Ward, and Jean-Baptiste Sallée
Biogeosciences, 22, 1947–1968, https://doi.org/10.5194/bg-22-1947-2025, https://doi.org/10.5194/bg-22-1947-2025, 2025
Short summary
Short summary
In summer 2022, a CARbon Interface OCean Atmosphere (CARIOCA) drifting buoy observed an anomalously strong ocean carbon sink in the subpolar Southern Ocean associated with large plumes of chlorophyll a. Lagrangian backward trajectories indicate that these waters originated from the sea ice edge in spring 2021. Our study highlights the northward migration of the CO2 sink associated with early sea ice retreat.
Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, Bruno Bombled, Jacqueline Boutin, Yann Bozec, Steeve Comeau, Pascal Conan, Laurent Coppola, Pascale Cuet, Eva Ferreira, Jean-Pierre Gattuso, Frédéric Gazeau, Catherine Goyet, Emilie Grossteffan, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Coraline Leseurre, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Peggy Rimmelin-Maury, Jean-François Ternon, Franck Touratier, Aline Tribollet, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 17, 1075–1100, https://doi.org/10.5194/essd-17-1075-2025, https://doi.org/10.5194/essd-17-1075-2025, 2025
Short summary
Short summary
This work presents a new synthesis of 67 000 total alkalinity and total dissolved inorganic carbon observations obtained between 1993 and 2023 in the global ocean, coastal zones, and the Mediterranean Sea. We describe the data assemblage and associated quality control and discuss some potential uses of this dataset. The dataset is provided in a single format and includes the quality flag for each sample.
Clovis Thouvenin-Masson, Jacqueline Boutin, Vincent Échevin, Alban Lazar, and Jean-Luc Vergely
Ocean Sci., 20, 1547–1566, https://doi.org/10.5194/os-20-1547-2024, https://doi.org/10.5194/os-20-1547-2024, 2024
Short summary
Short summary
We focus on understanding the impact of river runoff and precipitation on sea surface salinity (SSS) in the eastern North Tropical Atlantic (e-NTA) region off northwestern Africa. By analyzing regional simulations and observational data, we find that river flows significantly influence SSS variability, particularly after the rainy season. Our findings underscore that a main source of uncertainty representing SSS variability in this region is from river runoff estimates.
Charlotte A. J. Williams, Tom Hull, Jan Kaiser, Claire Mahaffey, Naomi Greenwood, Matthew Toberman, and Matthew R. Palmer
Biogeosciences, 21, 1961–1971, https://doi.org/10.5194/bg-21-1961-2024, https://doi.org/10.5194/bg-21-1961-2024, 2024
Short summary
Short summary
Oxygen (O2) is a key indicator of ocean health. The risk of O2 loss in the productive coastal/continental slope regions is increasing. Autonomous underwater vehicles equipped with O2 optodes provide lots of data but have problems resolving strong vertical O2 changes. Here we show how to overcome this and calculate how much O2 is supplied to the low-O2 bottom waters via mixing. Bursts in mixing supply nearly all of the O2 to bottom waters in autumn, stopping them reaching ecologically low levels.
Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, David Antoine, Guillaume Bourdin, Jacqueline Boutin, Yann Bozec, Pascal Conan, Laurent Coppola, Frédéric Diaz, Eric Douville, Xavier Durrieu de Madron, Jean-Pierre Gattuso, Frédéric Gazeau, Melek Golbol, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Fabien Lombard, Férial Louanchi, Liliane Merlivat, Léa Olivier, Anne Petrenko, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Aline Tribollet, Vincenzo Vellucci, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 16, 89–120, https://doi.org/10.5194/essd-16-89-2024, https://doi.org/10.5194/essd-16-89-2024, 2024
Short summary
Short summary
This work presents a synthesis of 44 000 total alkalinity and dissolved inorganic carbon observations obtained between 1993 and 2022 in the Global Ocean and the Mediterranean Sea at the surface and in the water column. Seawater samples were measured using the same method and calibrated with international Certified Reference Material. We describe the data assemblage, quality control and some potential uses of this dataset.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
Short summary
Short summary
The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Ria Oelerich, Karen J. Heywood, Gillian M. Damerell, Marcel du Plessis, Louise C. Biddle, and Sebastiaan Swart
Ocean Sci., 19, 1465–1482, https://doi.org/10.5194/os-19-1465-2023, https://doi.org/10.5194/os-19-1465-2023, 2023
Short summary
Short summary
At the southern boundary of the Antarctic Circumpolar Current, relatively warm waters encounter the colder waters surrounding Antarctica. Observations from underwater vehicles and altimetry show that medium-sized cold-core eddies influence the southern boundary's barrier properties by strengthening the slopes of constant density lines across it and amplifying its associated jet. As a result, the ability of exchanging properties, such as heat, across the southern boundary is reduced.
Amelia M. H. Bond, Markus M. Frey, Jan Kaiser, Jörg Kleffmann, Anna E. Jones, and Freya A. Squires
Atmos. Chem. Phys., 23, 5533–5550, https://doi.org/10.5194/acp-23-5533-2023, https://doi.org/10.5194/acp-23-5533-2023, 2023
Short summary
Short summary
Atmospheric nitrous acid (HONO) amount fractions measured at Halley Research Station, Antarctica, were found to be low. Vertical fluxes of HONO from the snow were also measured and agree with the estimated HONO production rate from photolysis of snow nitrate. In a simple box model of HONO sources and sinks, there was good agreement between the measured flux and amount fraction. HONO was found to be an important OH radical source at Halley.
Pierre L'Hégaret, Florian Schütte, Sabrina Speich, Gilles Reverdin, Dariusz B. Baranowski, Rena Czeschel, Tim Fischer, Gregory R. Foltz, Karen J. Heywood, Gerd Krahmann, Rémi Laxenaire, Caroline Le Bihan, Philippe Le Bot, Stéphane Leizour, Callum Rollo, Michael Schlundt, Elizabeth Siddle, Corentin Subirade, Dongxiao Zhang, and Johannes Karstensen
Earth Syst. Sci. Data, 15, 1801–1830, https://doi.org/10.5194/essd-15-1801-2023, https://doi.org/10.5194/essd-15-1801-2023, 2023
Short summary
Short summary
In early 2020, the EUREC4A-OA/ATOMIC experiment took place in the northwestern Tropical Atlantic Ocean, a dynamical region where different water masses interact. Four oceanographic vessels and a fleet of autonomous devices were deployed to study the processes at play and sample the upper ocean, each with its own observing capability. The article first describes the data calibration and validation and second their cross-validation, using a hierarchy of instruments and estimating the uncertainty.
Peter M. F. Sheehan, Gillian M. Damerell, Philip J. Leadbitter, Karen J. Heywood, and Rob A. Hall
Ocean Sci., 19, 77–92, https://doi.org/10.5194/os-19-77-2023, https://doi.org/10.5194/os-19-77-2023, 2023
Short summary
Short summary
We calculate the rate of turbulent kinetic energy dissipation, i.e. the mixing driven by small-scale ocean turbulence, in the western tropical Atlantic Ocean via two methods. We find good agreement between the results of both. A region of elevated mixing is found between 200 and 500 m, and we calculate the associated heat and salt fluxes. We find that double-diffusive mixing in salt fingers, a common feature of the tropical oceans, drives larger heat and salt fluxes than the turbulent mixing.
Callum Rollo, Karen J. Heywood, and Rob A. Hall
Geosci. Instrum. Method. Data Syst., 11, 359–373, https://doi.org/10.5194/gi-11-359-2022, https://doi.org/10.5194/gi-11-359-2022, 2022
Short summary
Short summary
Using an underwater buoyancy-powered autonomous glider, we collected profiles of temperature and salinity from the ocean north-east of Barbados. Most of the temperature and salinity profiles contained staircase-like structures of alternating constant values and large gradients. We wrote an algorithm to identify these staircases. We hypothesise that these staircases are prevented from forming where background gradients in temperature and salinity are too great.
Elise S. Droste, Mario Hoppema, Melchor González-Dávila, Juana Magdalena Santana-Casiano, Bastien Y. Queste, Giorgio Dall'Olmo, Hugh J. Venables, Gerd Rohardt, Sharyn Ossebaar, Daniel Schuller, Sunke Trace-Kleeberg, and Dorothee C. E. Bakker
Ocean Sci., 18, 1293–1320, https://doi.org/10.5194/os-18-1293-2022, https://doi.org/10.5194/os-18-1293-2022, 2022
Short summary
Short summary
Tides affect the marine carbonate chemistry of a coastal polynya neighbouring the Ekström Ice Shelf by movement of seawater with different physical and biogeochemical properties. The result is that the coastal polynya in the summer can switch between being a sink or a source of CO2 multiple times a day. We encourage consideration of tides when collecting in polar coastal regions to account for tide-driven variability and to avoid overestimations or underestimations of air–sea CO2 exchange.
Benjamin R. Loveday, Timothy Smyth, Anıl Akpinar, Tom Hull, Mark E. Inall, Jan Kaiser, Bastien Y. Queste, Matt Tobermann, Charlotte A. J. Williams, and Matthew R. Palmer
Earth Syst. Sci. Data, 14, 3997–4016, https://doi.org/10.5194/essd-14-3997-2022, https://doi.org/10.5194/essd-14-3997-2022, 2022
Short summary
Short summary
Using a new approach to combine autonomous underwater glider data and satellite Earth observations, we have generated a 19-month time series of North Sea net primary productivity – the rate at which phytoplankton absorbs carbon dioxide minus that lost through respiration. This time series, which spans 13 gliders, allows for new investigations into small-scale, high-frequency variability in the biogeochemical processes that underpin the carbon cycle and coastal marine ecosystems in shelf seas.
Michael P. Hemming, Jan Kaiser, Jacqueline Boutin, Liliane Merlivat, Karen J. Heywood, Dorothee C. E. Bakker, Gareth A. Lee, Marcos Cobas García, David Antoine, and Kiminori Shitashima
Ocean Sci., 18, 1245–1262, https://doi.org/10.5194/os-18-1245-2022, https://doi.org/10.5194/os-18-1245-2022, 2022
Short summary
Short summary
An underwater glider mission was carried out in spring 2016 near a mooring in the northwestern Mediterranean Sea. The glider deployment served as a test of a prototype ion-sensitive field-effect transistor pH sensor. Mean net community production rates were estimated from glider and buoy measurements of dissolved oxygen and inorganic carbon concentrations before and during the spring bloom. Incorporating advection is important for accurate mass budgets. Unexpected metabolic quotients were found.
Liliane Merlivat, Michael Hemming, Jacqueline Boutin, David Antoine, Vincenzo Vellucci, Melek Golbol, Gareth A. Lee, and Laurence Beaumont
Biogeosciences, 19, 3911–3920, https://doi.org/10.5194/bg-19-3911-2022, https://doi.org/10.5194/bg-19-3911-2022, 2022
Short summary
Short summary
We use in situ high-temporal-resolution measurements of dissolved inorganic carbon and atmospheric parameters at the air–sea interface to analyse phytoplankton bloom initiation identified as the net rate of biological carbon uptake in the Mediterranean Sea. The shift from wind-driven to buoyancy-driven mixing creates conditions for blooms to begin. Active mixing at the air–sea interface leads to the onset of the surface phytoplankton bloom due to the relaxation of wind speed following storms.
Yixi Zheng, David P. Stevens, Karen J. Heywood, Benjamin G. M. Webber, and Bastien Y. Queste
The Cryosphere, 16, 3005–3019, https://doi.org/10.5194/tc-16-3005-2022, https://doi.org/10.5194/tc-16-3005-2022, 2022
Short summary
Short summary
New observations reveal the Thwaites gyre in a habitually ice-covered region in the Amundsen Sea for the first time. This gyre rotates anticlockwise, despite the wind here favouring clockwise gyres like the Pine Island Bay gyre – the only other ocean gyre reported in the Amundsen Sea. We use an ocean model to suggest that sea ice alters the wind stress felt by the ocean and hence determines the gyre direction and strength. These processes may also be applied to other gyres in polar oceans.
Josué Bock, Jan Kaiser, Max Thomas, Andreas Bott, and Roland von Glasow
Geosci. Model Dev., 15, 5807–5828, https://doi.org/10.5194/gmd-15-5807-2022, https://doi.org/10.5194/gmd-15-5807-2022, 2022
Short summary
Short summary
MISTRA-v9.0 is an atmospheric boundary layer chemistry model. The model includes a detailed particle description with regards to the microphysics, gas–particle interactions, and liquid phase chemistry within particles. Version 9.0 is the first release of MISTRA as an open-source community model. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA with good consistency.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Nathalie Lefèvre, Peter Landschützer, Sabrina Speich, Johannes Karstensen, Matthieu Labaste, Christophe Noisel, Markus Ritschel, Tobias Steinhoff, and Rik Wanninkhof
Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, https://doi.org/10.5194/bg-19-2969-2022, 2022
Short summary
Short summary
We investigate the impact of the interactions between eddies and the Amazon River plume on the CO2 air–sea fluxes to better characterize the ocean carbon sink in winter 2020. The region is a strong CO2 sink, previously underestimated by a factor of 10 due to a lack of data and understanding of the processes responsible for the variability in ocean carbon parameters. The CO2 absorption is mainly driven by freshwater from the Amazon entrained by eddies and by the winter seasonal cooling.
Yanxin Wang, Karen J. Heywood, David P. Stevens, and Gillian M. Damerell
Ocean Sci., 18, 839–855, https://doi.org/10.5194/os-18-839-2022, https://doi.org/10.5194/os-18-839-2022, 2022
Short summary
Short summary
It is important that climate models give accurate projections of future extremes in summer and winter sea surface temperature because these affect many features of the global climate system. Our results demonstrate that some models would give large errors if used for future projections of these features, and models with more detailed representation of vertical structure in the ocean tend to have a better representation of sea surface temperature, particularly in summer.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Corinne Le Quéré, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Rob B. Jackson, Simone R. Alin, Peter Anthoni, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Laurent Bopp, Thi Tuyet Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Kim I. Currie, Bertrand Decharme, Laique M. Djeutchouang, Xinyu Dou, Wiley Evans, Richard A. Feely, Liang Feng, Thomas Gasser, Dennis Gilfillan, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Ingrid T. Luijkx, Atul Jain, Steve D. Jones, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Sebastian Lienert, Junjie Liu, Gregg Marland, Patrick C. McGuire, Joe R. Melton, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Clemens Schwingshackl, Roland Séférian, Adrienne J. Sutton, Colm Sweeney, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco Tubiello, Guido R. van der Werf, Nicolas Vuichard, Chisato Wada, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, and Jiye Zeng
Earth Syst. Sci. Data, 14, 1917–2005, https://doi.org/10.5194/essd-14-1917-2022, https://doi.org/10.5194/essd-14-1917-2022, 2022
Short summary
Short summary
The Global Carbon Budget 2021 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Monica Miranda Mugica, Christina Day, Brandon McHale, Kay Louis McGuinness, Gareth Lee, Daisy Pickup, and Nathan Scott Lawrence
Ocean Sci. Discuss., https://doi.org/10.5194/os-2021-126, https://doi.org/10.5194/os-2021-126, 2022
Revised manuscript not accepted
Short summary
Short summary
ANB Sensors has developed a novel solid-state technology for monitoring the pH of estuarine environments. It was shown to respond effectively to pH in laboratory environments where the pH of the sea water solution was manipulated by injections of CO2. Field tests were conducted in an estuarine environment close to Oban, Scotland. The sensor was validated against a sampled solution and the data highlighted the efficiency of the sensor to monitor the tidal variations of pH.
Tom Hull, Naomi Greenwood, Antony Birchill, Alexander Beaton, Matthew Palmer, and Jan Kaiser
Biogeosciences, 18, 6167–6180, https://doi.org/10.5194/bg-18-6167-2021, https://doi.org/10.5194/bg-18-6167-2021, 2021
Short summary
Short summary
The shallow shelf seas play a large role in the global cycling of CO2 and also support large fisheries. We use an autonomous underwater vehicle in the central North Sea to measure the rates of change in oxygen and nutrients.
Using these data we determine the amount of carbon dioxide taken out of the atmosphere by the sea and measure how productive the region is.
These observations will be useful for improving our predictive models and help us predict and adapt to a changing ocean.
Reiner Onken and Burkard Baschek
Ocean Sci. Discuss., https://doi.org/10.5194/os-2021-86, https://doi.org/10.5194/os-2021-86, 2021
Preprint withdrawn
Short summary
Short summary
The evolution of a small spiraliform ocean eddy is simulated with a numerical model. Its generation starts from a dense filament that is rolled into a vortex. Various quantities are organized in single-arm and multi-arm spirals. Oscillations of the vertical velocity are due to vortex Rossby waves. Virtual drifters and floats indicate downwelling everywhere near the surface, that is most intense in the center of the spiral, leading to a radial outflow and weak upwelling at the periphery.
Cited articles
Álvarez, M., Sanleón-Bartolomé, H., Tanhua, T., Mintrop, L., Luchetta, A., Cantoni, C., Schroeder, K., and Civitarese, G.: The CO2 system in the Mediterranean Sea: a basin wide perspective, Ocean Sci., 10, 69–92, https://doi.org/10.5194/os-10-69-2014, 2014.
Aßmann, S., Frank, C., and Körtzinger, A.: Spectrophotometric high-precision seawater pH determination for use in underway measuring systems, Ocean Sci., 7, 597–607, https://doi.org/10.5194/os-7-597-2011, 2011.
Bates, N. R., Best, M. H. P., Neely, K., Garley, R., Dickson, A. G., and Johnson, R. J.: Detecting anthropogenic carbon dioxide uptake and ocean acidification in the North Atlantic Ocean, Biogeosciences, 9, 2509–2522, https://doi.org/10.5194/bg-9-2509-2012, 2012.
Binetti, U.: Dissolved oxygen-based annual biological production from glider observations at the Porcupine Abyssal Plain (North Atlantic), Ph.D. thesis, University of East Anglia, 2016.
Bittig, H. C., Fiedler, B., Scholz, R., Krahmann, G., and Körtzinger, A.: Time response of oxygen optodes on profiling platforms and its dependence on flow speed and temperature, Limnol. Oceanogr. Methods, 12, 617–636, 2014.
Bresnahan, P. J., Martz, T. R., Takeshita, Y., Johnson, K. S., and LaShomb, M.: Best practices for autonomous measurement of seawater pH with the Honeywell Durafet, Methods Oceanogr., 9, 44–60, 2014.
Byrne, R. H. and Breland, J. A.: High precision multiwavelength pH determinations in seawater using cresol red, Deep Sea Res. A, 36, 803–810, 1989.
Copin-Montégut, C. and Bégovic, M.: Distributions of carbonate properties and oxygen along the water column (0–2000 m) in the central part of the NW Mediterranean Sea (Dyfamed site): influence of winter vertical mixing on air–sea CO2 and O2 exchanges, Deep Sea Res. II, 49, 2049–2066, 2002.
Cornwall, C. E., Hepburn, C. D., McGraw, C. M., Currie, K. I., Pilditch, C. A., Hunter, K. A., Boyd, P. W., and Hurd, C. L.: Diurnal fluctuations in seawater pH influence the response of a calcifying macroalga to ocean acidification, Proc. Roy. Soc. London B, 280, 20132 201, 2013.
Dickson, A.: pH scales and proton-transfer reactions in saline media such as sea water, Geochem. Cosmochim. Acta, 48, 2299–2308, 1984.
Dickson, A. and Millero, F. J.: A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media, Deep Sea Res. A, 34, 1733–1743, 1987.
Dickson, A. G.: Thermodynamics of the dissociation of boric acid in synthetic seawater from 273.15 to 318.15 K, Deep Sea Res. A, 37, 755–766, 1990.
Dickson, A. G., Sabine, C. L., and Christian, J. R.: Guide to best practices for ocean CO2 measurements, PICES Special Publication 3, 191 pp., 2007.
Doney, S. C., Fabry, V. J., Feely, R. A., and Kleypas, J. A.: Ocean acidification: the other CO2 problem, Marine Sci., 1, 169–192, 2009.
El Sayed, M. A., Aminot, A., and Kerouel, R.: Nutrients and trace metals in the northwestern Mediterranean under coastal upwelling conditions, Cont. Shelf Res., 14, 507–530, 1994.
Eriksen, C. C., Osse, T. J., Light, R. D., Wen, T., Lehman, T. W., Sabin, P. L., Ballard, J. W., and Chiodi, A. M.: Seaglider: A long-range autonomous underwater vehicle for oceanographic research, Oceanic Engineering, IEEE Journal of, 26, 424–436, 2001.
Estrada, M.: Primary production in the northwestern Mediterranean, Scientia Marina, 60, 55–64, 1996.
Fabry, V. J., Seibel, B. A., Feely, R. A., and Orr, J. C.: Impacts of ocean acidification on marine fauna and ecosystem processes, ICES Journal of Marine Science: Journal du Conseil, 65, 414–432, 2008.
Frajka-Williams, E., Eriksen, C. C., Rhines, P. B., and Harcourt, R. R.: Determining vertical water velocities from Seaglider, J. Atmos. Ocean. Tech., 28, 1641–1656, 2011.
Garau, B., Ruiz, S., Zhang, W. G., Pascual, A., Heslop, E., Kerfoot, J., and Tintoré, J.: Thermal lag correction on Slocum CTD glider data, J. Atmos. Ocean. Tech., 28, 1065–1071, 2011.
Hofmann, G. E., Smith, J. E., Johnson, K. S., Send, U., Levin, L. A., Micheli, F., Paytan, A., Price, N. N., Peterson, B., Takeshita, Y., Matson, P. G., Crook, E. D., Kroeker, K. J., Gambi, M. C., Rivest, E. B., Frieder, C. A., Yu, P. C., and Martz, T. R.: High-frequency dynamics of ocean pH: a multi-ecosystem comparison, PloS one, 6, e28983, https://doi.org/10.1371/journal.pone.0028983, 2011.
Johnson, K. M., King, A. E., and Sieburth, J. M.: Coulometric TCO2 analyses for marine studies; an introduction, Marine Chem., 16, 61–82, 1985.
Johnson, K. S., Jannasch, H. W., Coletti, L. J., Elrod, V. A., Martz, T. R., Takeshita, Y., Carlson, R. J., and Connery, J. G.: Deep-Sea DuraFET: A pressure tolerant pH sensor designed for global sensor networks, Anal. Chem., 88, 3249–3256, 2016.
Key, R. M., Tanhua, T., Olsen, A., Hoppema, M., Jutterström, S., Schirnick, C., van Heuven, S., Kozyr, A., Lin, X., Velo, A., Wallace, D. W. R., and Mintrop, L.: The CARINA data synthesis project: introduction and overview, Earth Syst. Sci. Data, 2, 105–121, https://doi.org/10.5194/essd-2-105-2010, 2010.
Knoll, M., Benecke, J., Russo, A., and Ampolo-Rella, M.: Comparison of CTD measurements obtained by NRV Alliance and RV Planet during REP14-MED, Technical Report WTD71-0083/2015 WB 34 pp., 2015b.
Le Quéré, C., Moriarty, R., Andrew, R. M., Peters, G. P., Ciais, P., Friedlingstein, P., Jones, S. D., Sitch, S., Tans, P., Arneth, A., Boden, T. A., Bopp, L., Bozec, Y., Canadell, J. G., Chini, L. P., Chevallier, F., Cosca, C. E., Harris, I., Hoppema, M., Houghton, R. A., House, J. I., Jain, A. K., Johannessen, T., Kato, E., Keeling, R. F., Kitidis, V., Klein Goldewijk, K., Koven, C., Landa, C. S., Landschützer, P., Lenton, A., Lima, I. D., Marland, G., Mathis, J. T., Metzl, N., Nojiri, Y., Olsen, A., Ono, T., Peng, S., Peters, W., Pfeil, B., Poulter, B., Raupach, M. R., Regnier, P., Rödenbeck, C., Saito, S., Salisbury, J. E., Schuster, U., Schwinger, J., Séférian, R., Segschneider, J., Steinhoff, T., Stocker, B. D., Sutton, A. J., Takahashi, T., Tilbrook, B., van der Werf, G. R., Viovy, N., Wang, Y.-P., Wanninkhof, R., Wiltshire, A., and Zeng, N.: Global carbon budget 2014, Earth Syst. Sci. Data, 7, 47–85, https://doi.org/10.5194/essd-7-47-2015, 2015.
Lefèvre, N. and Merlivat, L.: Carbon and oxygen net community production in the eastern tropical Atlantic estimated from a moored buoy, Global Biogeochem. Cy., 26, https://doi.org/10.1029/2010GB004018, 2012.
Liao, H.-K., Wu, C.-L., Chou, J.-C., Chung, W.-Y., Sun, T.-P., and Hsiung, S.-K.: Multi-structure ion sensitive field effect transistor with a metal light shield, Sensors and Actuators B: Chemical, 61, 1–5, 1999.
Martz, T. R., Carr, J. J., French, C. R., and DeGrandpre, M. D.: A submersible autonomous sensor for spectrophotometric pH measurements of natural waters, Anal. Chem., 75, 1844–1850, 2003.
Martz, T. R., Connery, J. G., and Johnson, K. S.: Testing the Honeywell Durafet® for seawater pH applications, Limnol. Oceanogr. Methods, 8, 172–184, 2010.
McNeil, C. L. and D'Asaro, E. A.: A calibration equation for oxygen optodes based on physical properties of the sensing foil, Limnol. Oceanogr. Methods, 12, 139–154, 2014.
Mehrbach, C., Culberson, C., Hawley, J., and Pytkowics, R.: Measurement of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure, Limnol. Oceanogr., 18, 40 pp., 1973.
Merlivat, L., Boutin, J., and Antoine, D.: Roles of biological and physical processes in driving seasonal air–sea CO2 flux in the southern ocean: new insights from CARIOCA pCO2, J. Marine Syst., 147, 9–20, 2015.
Millero, F. J.: Thermodynamics of the carbon dioxide system in the oceans, Geochim. Cosmochim. Acta, 59, 661–677, 1995.
Millot, C.: Circulation in the western Mediterranean Sea, J. Marine Syst., 20, 423–442, 1999.
Mintrop, L., Pérez, F. F., González-Dávila, M., Santana-Casiano, M., and Körtzinger, A.: Alkalinity determination by potentiometry: Intercalibration using three different methods, Ciencias Marinas, 26, 23–37, 2000.
NATO Centre for Maritime Research and Experimentation (CMRE): Geo Spatial Data Portal, available at: http://geos3.cmre.nato.int/portal, last access: May 2016.
Olita, A., Ribotti, A., Fazioli, L., Perilli, A., and Sorgente, R.: Surface circulation and upwelling in the Sardinia Sea: A numerical study, Cont. Shelf Res., 71, 95–108, 2013.
Onken, R., Fiekas, H.-V., Beguery, L., Borrione, I., Funk, A., Hemming, M., Heywood, K. J., Kaiser, J., Knoll, M., Poulain, P.-M., Queste, B., Russo, A., Shitashima, K., Siderius, M., and Thorp-Küsel, E.: High-Resolution Observations in the Western Mediterranean Sea: The REP14-MED Experiment, Ocean Sci. Discuss., https://doi.org/10.5194/os-2016-82, in review, 2016.
Orr, J. C., Epitalon, J.-M., and Gattuso, J.-P.: Comparison of ten packages that compute ocean carbonate chemistry, Biogeosciences, 12, 1483–1510, https://doi.org/10.5194/bg-12-1483-2015, 2015.
Piterbarg, L., Taillandier, V., and Griffa, A.: Investigating frontal variability from repeated glider transects in the Ligurian Current (North West Mediterranean Sea), J. Marine Syst., 129, 381–395, 2014.
Porter, M., Inall, M., Hopkins, J., Palmer, M., Dale, A., Aleynik, D., Barth, J., Mahaffey, C., and Smeed, D.: Glider observations of enhanced deep water upwelling at a shelf break canyon: A mechanism for cross-slope carbon and nutrient exchange, J. Geophys. Res.-Oceans, 121, 7575–7588, 2016.
Queste, B. Y., Heywood, K. J., Kaiser, J., Lee, G., Matthews, A., Schmidtko, S., Walker-Brown, C., and Woodward, S. W.: Deployments in extreme conditions: Pushing the boundaries of Seaglider capabilities, in: Autonomous Underwater Vehicles (AUV), 2012 IEEE/OES, 1–7, IEEE, 2012.
Rhein, M., Rintoul, S., Aoki, S., Campos, E., Chambers, D., Feely, R., Gulev, S., Johnson, G., Josey, S., Kostianoy, A., Mauritzen, C., Roemmich, D., Talley, L. D., and Wang, F.: Chapter 3: Observations: Ocean, Climate Change, 255–315, 2013.
Rivaro, P., Messa, R., Massolo, S., and Frache, R.: Distributions of carbonate properties along the water column in the Mediterranean Sea: Spatial and temporal variations, Marine Chem., 121, 236–245, 2010.
Roemmich, D. H., Davis, R. E., Riser, S. C., Owens, W. B., Molinari, R. L., Garzoli, S. L., and Johnson, G. C.: The argo project. global ocean observations for understanding and prediction of climate variability, Tech. rep., DTIC Document, 2003.
Roughan, M., Terrill, E. J., Largier, J. L., and Otero, M. P.: Observations of divergence and upwelling around Point Loma, California, J. Geophys. Res.-Oceans, 110, C04011, https://doi.org/10.1029/2004JC002662, 2005.
Shitashima, K.: Evolution of compact electrochemical in-situ pH-pCO2 sensor using ISFET-pH electrode, in: Oceans 2010 MTS/IEEE Seattle, 1–4, 2010.
Shitashima, K., Kyo, M., Koike, Y., and Henmi, H.: Development of in situ pH sensor using ISFET, in: Underwater Technology, 2002. Proceedings of the 2002 International Symposium on, 106–108, IEEE, 2002.
Shitashima, K., Maeda, Y., and Ohsumi, T.: Development of detection and monitoring techniques of CO2 leakage from seafloor in sub-seabed CO2 storage, Appl. Geochem., 30, 114–124, 2013.
Takeshita, Y., Martz, T. R., Johnson, K. S., and Dickson, A. G.: Characterization of an ion sensitive field effect transistor and chloride ion selective electrodes for pH measurements in seawater, Anal. Chem., 86, 11189–11195, 2014.
Touratier, F. and Goyet, C.: Impact of the Eastern Mediterranean Transient on the distribution of anthropogenic CO2 and first estimate of acidification for the Mediterranean Sea, Deep Sea Res. I, 58, 1–15, 2011.
Uppström, L. R.: The boron/chlorinity ratio of deep-sea water from the Pacific Ocean, in: Deep Sea Research and Oceanographic Abstracts, vol. 21, 161–162, Elsevier, 1974.
Van Heuven, S., Pierrot, D., Rae, J., Lewis, E., and Wallace, D.: MATLAB program developed for CO2 system calculations, ORNL/CDIAC-105b, Carbon Dioxide Inf, Anal. Cent., Oak Ridge Natl. Lab., US DOE, Oak Ridge, Tennessee, 2011.
Wlodarski, W., Bergveld, P., and Voorthuyzen, J.: Threshold voltage variations in n-channel MOS transistors and MOSFET-based sensors due to optical radiation, Sensors and Actuators, 9, 313–321, 1986.
Yao, K. M., Marcou, O., Goyet, C., Guglielmi, V., Touratier, F., and Savy, J.-P.: Time variability of the north-western Mediterranean Sea pH over 1995–2011, Marine Environ. Res., 116, 51–60, 2016.
Yates, K. K., Dufore, C., Smiley, N., Jackson, C., and Halley, R. B.: Diurnal variation of oxygen and carbonate system parameters in Tampa Bay and Florida Bay, Marine Chem., 104, 110–124, 2007.
Zeebe, R. E. and Wolf-Gladrow, D. A.: CO2 in seawater: equilibrium, kinetics, isotopes, Gulf Professional Publishing, 2001.
Short summary
Underwater gliders are useful platforms for monitoring the world oceans at a high resolution. An experimental pH sensor was attached to an underwater glider in the Mediterranean Sea, which is an important carbon sink region. Comparing measurements from the glider with those obtained from a ship indicated that there were issues with the experimental pH sensor. Correcting for these issues enabled us to look at pH variability in the area related to biomass abundance and physical water properties.
Underwater gliders are useful platforms for monitoring the world oceans at a high resolution. An...
