Articles | Volume 16, issue 4
https://doi.org/10.5194/os-16-847-2020
https://doi.org/10.5194/os-16-847-2020
Research article
 | 
21 Jul 2020
Research article |  | 21 Jul 2020

Current estimates of K1* and K2* appear inconsistent with measured CO2 system parameters in cold oceanic regions

Olivier Sulpis, Siv K. Lauvset, and Mathilde Hagens

Related authors

Impacts of CICE sea ice model and ERA atmosphere on an Antarctic MetROMS ocean model, MetROMS-UHel-v1.0
Cecilia Äijälä, Yafei Nie, Lucía Gutiérrez-Loza, Chiara De Falco, Siv Kari Lauvset, Bin Cheng, David A. Bailey, and Petteri Uotila
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-213,https://doi.org/10.5194/gmd-2024-213, 2024
Preprint under review for GMD
Short summary
Global Carbon Budget 2024
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Carla F. Berghoff, Henry C. Bittig, Laurent Bopp, Patricia Cadule, Katie Campbell, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Thomas Colligan, Jeanne Decayeux, Laique Djeutchouang, Xinyu Dou, Carolina Duran Rojas, Kazutaka Enyo, Wiley Evans, Amanda Fay, Richard A. Feely, Daniel J. Ford, Adrianna Foster, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Siv K. Lauvset, Nathalie Lefèvre, Zhu Liu, Junjie Liu, Lei Ma, Shamil Maksyutov, Gregg Marland, Nicolas Mayot, Patrick McGuire, Nicolas Metzl, Natalie M. Monacci, Eric J. Morgan, Shin-Ichiro Nakaoka, Craig Neill, Yosuke Niwa, Tobias Nützel, Lea Olivier, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Zhangcai Qin, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, T. Luke Smallman, Stephen Smith, Reinel Sospedra-Alfonso, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Bronte Tilbrook, Olivier Torres, Etienne Tourigny, Hiroyuki Tsujino, Francesco Tubiello, Guido van der Werf, Rik Wanninkhof, Xuhui Wang, Dongxu Yang, Xiaojuan Yang, Zhen Yu, Wenping Yuan, Xu Yue, Sönke Zaehle, Ning Zeng, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-519,https://doi.org/10.5194/essd-2024-519, 2024
Preprint under review for ESSD
Short summary
A consistent regional dataset of dissolved oxygen in the Western Mediterranean Sea (2004–2023): O2WMED
Malek Belgacem, Katrin Schroeder, Siv K. Lauvset, Marta Álvarez, Jacopo Chiggiato, Mireno Borghini, Carolina Cantoni, Tiziana Ciuffardi, and Stefania Sparnocchia
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-365,https://doi.org/10.5194/essd-2024-365, 2024
Preprint under review for ESSD
Short summary
The annual update GLODAPv2.2023: the global interior ocean biogeochemical data product
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024,https://doi.org/10.5194/essd-16-2047-2024, 2024
Short summary
Synthesis Product for Ocean Time Series (SPOTS) – a ship-based biogeochemical pilot
Nico Lange, Björn Fiedler, Marta Álvarez, Alice Benoit-Cattin, Heather Benway, Pier Luigi Buttigieg, Laurent Coppola, Kim Currie, Susana Flecha, Dana S. Gerlach, Makio Honda, I. Emma Huertas, Siv K. Lauvset, Frank Muller-Karger, Arne Körtzinger, Kevin M. O'Brien, Sólveig R. Ólafsdóttir, Fernando C. Pacheco, Digna Rueda-Roa, Ingunn Skjelvan, Masahide Wakita, Angelicque White, and Toste Tanhua
Earth Syst. Sci. Data, 16, 1901–1931, https://doi.org/10.5194/essd-16-1901-2024,https://doi.org/10.5194/essd-16-1901-2024, 2024
Short summary

Cited articles

Bailey, N., Papakyriakou, T. N., Bartels, C., and Feiyue, W.: Henry's Law constant for CO2 in aqueous sodium chloride solutions at 1 atm and sub-zero (Celsius) temperatures, Mar. Chem., 207, 26–32, https://doi.org/10.1016/j.marchem.2018.10.003, 2018. 
Bates, N. R.: Ocean Carbon Cycle, in: Encyclopedia of Ocean Sciences, 3rd edn., edited by: Cochran, J. K., Bokuniewicz, H. J., and Yager, P. L., Elsevier, 1, 418–428, 2019. 
Brown, K. A., Miller, L. A., Davelaar, M., Francois, R., and Tortell, P. D.: Over-determination of the carbonate system in natural sea-ice brine and assessment of carbonic acid dissociation constants under low temperature, high salinity conditions, Mar. Chem., 165, 36–45, https://doi.org/10.1016/j.marchem.2014.07.005, 2014. 
Byrne, R. H. and Yao, W.: Procedures for measurement of carbonate ion concentrations in seawater by direct spectrophotometric observations of Pb(II) complexation, Mar. Chem., 112, 128–135, 2008. 
Download
Short summary
As direct measurements of seawater carbonate system variables, such as pH, are difficult to obtain, scientists use equilibrium constants to compute them from known variables. Using a compilation of in situ data, we show that the set of equilibrium constants preferred by the community is not consistent with measurements in cold, polar waters, where human-made ocean acidification is spreading rapidly. Closing knowledge gaps regarding seawater carbon chemistry in polar regions should be a priority.