Articles | Volume 16, issue 4
https://doi.org/10.5194/os-16-847-2020
https://doi.org/10.5194/os-16-847-2020
Research article
 | 
21 Jul 2020
Research article |  | 21 Jul 2020

Current estimates of K1* and K2* appear inconsistent with measured CO2 system parameters in cold oceanic regions

Olivier Sulpis, Siv K. Lauvset, and Mathilde Hagens

Related authors

Remineralisation changes dominate oxygen variability in the North Atlantic
Rachael N. C. Sanders, Elaine L. McDonagh, Siv K. Lauvset, Charles E. Turner, Thomas W. N. Haine, Nadine Goris, and Richard Sanders
EGUsphere, https://doi.org/10.5194/egusphere-2025-3729,https://doi.org/10.5194/egusphere-2025-3729, 2025
This preprint is open for discussion and under review for Ocean Science (OS).
Short summary
Impacts of the CICE sea ice model and ERA atmosphere on an Antarctic MetROMS ocean model, MetROMS-UHel-v1.0
Cecilia Äijälä, Yafei Nie, Lucía Gutiérrez-Loza, Chiara De Falco, Siv Kari Lauvset, Bin Cheng, David Anthony Bailey, and Petteri Uotila
Geosci. Model Dev., 18, 4823–4853, https://doi.org/10.5194/gmd-18-4823-2025,https://doi.org/10.5194/gmd-18-4823-2025, 2025
Short summary
Earth system models overestimate the sensitivity of apparent oxygen utilisation to age change in the deep ocean
Damien Couespel, Xabier Davila, Nadine Goris, Emil Jeansson, Siv K. Lauvset, and Jerry Tjiputra
EGUsphere, https://doi.org/10.5194/egusphere-2025-2566,https://doi.org/10.5194/egusphere-2025-2566, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Reviews and syntheses: Carbon vs. cation based MRV of Enhanced Rock Weathering and the issue of soil organic carbon
Jelle Bijma, Mathilde Hagens, Jens Hammes, Noah Planavsky, Philip A. E. Pogge von Strandmann, Tom Reershemius, Christopher T. Reinhard, Phil Renforth, Tim Jesper Suhrhoff, Sara Vicca, Arthur Vienne, and Dieter A. Wolf-Gladrow
EGUsphere, https://doi.org/10.5194/egusphere-2025-2740,https://doi.org/10.5194/egusphere-2025-2740, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Synthesis of data products for ocean carbonate chemistry
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Luke Gregor, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Yosuke Iida, Masao Ishii, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, Alizée Roobaert, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Hyelim Yoo, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-255,https://doi.org/10.5194/essd-2025-255, 2025
Preprint under review for ESSD
Short summary

Cited articles

Bailey, N., Papakyriakou, T. N., Bartels, C., and Feiyue, W.: Henry's Law constant for CO2 in aqueous sodium chloride solutions at 1 atm and sub-zero (Celsius) temperatures, Mar. Chem., 207, 26–32, https://doi.org/10.1016/j.marchem.2018.10.003, 2018. 
Bates, N. R.: Ocean Carbon Cycle, in: Encyclopedia of Ocean Sciences, 3rd edn., edited by: Cochran, J. K., Bokuniewicz, H. J., and Yager, P. L., Elsevier, 1, 418–428, 2019. 
Brown, K. A., Miller, L. A., Davelaar, M., Francois, R., and Tortell, P. D.: Over-determination of the carbonate system in natural sea-ice brine and assessment of carbonic acid dissociation constants under low temperature, high salinity conditions, Mar. Chem., 165, 36–45, https://doi.org/10.1016/j.marchem.2014.07.005, 2014. 
Byrne, R. H. and Yao, W.: Procedures for measurement of carbonate ion concentrations in seawater by direct spectrophotometric observations of Pb(II) complexation, Mar. Chem., 112, 128–135, 2008. 
Download
Short summary
As direct measurements of seawater carbonate system variables, such as pH, are difficult to obtain, scientists use equilibrium constants to compute them from known variables. Using a compilation of in situ data, we show that the set of equilibrium constants preferred by the community is not consistent with measurements in cold, polar waters, where human-made ocean acidification is spreading rapidly. Closing knowledge gaps regarding seawater carbon chemistry in polar regions should be a priority.
Share