Articles | Volume 15, issue 1
https://doi.org/10.5194/os-15-33-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/os-15-33-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmospheric histories, growth rates and solubilities in seawater and other natural waters of the potential transient tracers HCFC-22, HCFC-141b, HCFC-142b, HFC-134a, HFC-125, HFC-23, PFC-14 and PFC-116
Pingyang Li
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, 24105 Kiel, Germany
Jens Mühle
Scripps Institution of Oceanography, University of California, San
Diego, La Jolla, California 92093, USA
Stephen A. Montzka
Earth System Research Laboratory, National Oceanic and Atmospheric
Administration, Boulder, Colorado 80305, USA
David E. Oram
National Centre for Atmospheric Science, Centre for Ocean and
Atmospheric Sciences, School of Environmental Sciences, University of East
Anglia, Norwich, NR4 7TJ, UK
Benjamin R. Miller
Earth System Research Laboratory, National Oceanic and Atmospheric
Administration, Boulder, Colorado 80305, USA
Ray F. Weiss
Scripps Institution of Oceanography, University of California, San
Diego, La Jolla, California 92093, USA
Paul J. Fraser
Climate Science Centre, Commonwealth Scientific and Industrial
Research Organization Oceans and Atmosphere, Aspendale, Victoria, 3195,
Australia
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, 24105 Kiel, Germany
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Cited
12 citations as recorded by crossref.
- Exploration of the environmental and socioeconomic implications of HCFC-22 phase-out for Botswana B. Kudoma & M. Tekere 10.1016/j.accre.2020.12.002
- Compilation of Henry's law constants (version 5.0.0) for water as solvent R. Sander 10.5194/acp-23-10901-2023
- Swiss halocarbon emissions for 2019 to 2020 assessed from regional atmospheric observations D. Rust et al. 10.5194/acp-22-2447-2022
- Recent Changes in Deep Ventilation of the Mediterranean Sea; Evidence From Long-Term Transient Tracer Observations P. Li & T. Tanhua 10.3389/fmars.2020.00594
- On the Influence of Hydroxyl Radical Changes and Ocean Sinks on Estimated HCFC and HFC Emissions and Banks P. Wang et al. 10.1029/2023GL105472
- Characteristics investigation of R407C in high voltage applications as an alternative to SF6 I. Khattak et al. 10.1016/j.rineng.2025.106627
- Progress in the development and use of refrigerants and unintended environmental consequences A. Vuppaladadiyam et al. 10.1016/j.scitotenv.2022.153670
- Atmospheric chemistry of CF3CHFCF2OCH3 (HFE-356mec3) and CHF2CHFOCF3 (HFE-236ea1) initiated by OH and Cl and their contribution to global warming S. Espinosa et al. 10.1007/s11356-024-34374-8
- The first satellite measurements of HFC-125 by the ACE-FTS: Long-term trends and distribution in the Earth’s upper troposphere and lower stratosphere R. Dodangodage et al. 10.1016/j.jqsrt.2024.109218
- Polyurethane Materials for Fire Retardancy: Synthesis, Structure, Properties, and Applications J. Zhang et al. 10.3390/fire8020064
- Extremely rapid self-reactions of hydrochlorofluoromethanes and hydrochlorofluoroethanes and implications in destruction of ozone Y. Xiao et al. 10.1016/j.cplett.2021.138867
- Medusa–Aqua system: simultaneous measurement and evaluation of novel potential halogenated transient tracers HCFCs, HFCs, and PFCs in the ocean P. Li & T. Tanhua 10.5194/os-17-509-2021
12 citations as recorded by crossref.
- Exploration of the environmental and socioeconomic implications of HCFC-22 phase-out for Botswana B. Kudoma & M. Tekere 10.1016/j.accre.2020.12.002
- Compilation of Henry's law constants (version 5.0.0) for water as solvent R. Sander 10.5194/acp-23-10901-2023
- Swiss halocarbon emissions for 2019 to 2020 assessed from regional atmospheric observations D. Rust et al. 10.5194/acp-22-2447-2022
- Recent Changes in Deep Ventilation of the Mediterranean Sea; Evidence From Long-Term Transient Tracer Observations P. Li & T. Tanhua 10.3389/fmars.2020.00594
- On the Influence of Hydroxyl Radical Changes and Ocean Sinks on Estimated HCFC and HFC Emissions and Banks P. Wang et al. 10.1029/2023GL105472
- Characteristics investigation of R407C in high voltage applications as an alternative to SF6 I. Khattak et al. 10.1016/j.rineng.2025.106627
- Progress in the development and use of refrigerants and unintended environmental consequences A. Vuppaladadiyam et al. 10.1016/j.scitotenv.2022.153670
- Atmospheric chemistry of CF3CHFCF2OCH3 (HFE-356mec3) and CHF2CHFOCF3 (HFE-236ea1) initiated by OH and Cl and their contribution to global warming S. Espinosa et al. 10.1007/s11356-024-34374-8
- The first satellite measurements of HFC-125 by the ACE-FTS: Long-term trends and distribution in the Earth’s upper troposphere and lower stratosphere R. Dodangodage et al. 10.1016/j.jqsrt.2024.109218
- Polyurethane Materials for Fire Retardancy: Synthesis, Structure, Properties, and Applications J. Zhang et al. 10.3390/fire8020064
- Extremely rapid self-reactions of hydrochlorofluoromethanes and hydrochlorofluoroethanes and implications in destruction of ozone Y. Xiao et al. 10.1016/j.cplett.2021.138867
- Medusa–Aqua system: simultaneous measurement and evaluation of novel potential halogenated transient tracers HCFCs, HFCs, and PFCs in the ocean P. Li & T. Tanhua 10.5194/os-17-509-2021
Latest update: 27 Aug 2025
Short summary
Use of CFCs as oceanic transient tracers is difficult for recently ventilated water masses as their atmospheric mole fractions have been decreasing. To explore novel tracers, we synthesized consistent annual mean atmospheric histories of HCFC-22, HCFC-141b, HCFC-142b, HFC-134a, HFC-125, HFC-23, PFC-14 (CF4) and PFC-116 in both hemispheres and reconstructed their solubility functions in water and seawater. This work is also potentially useful for tracer studies in a range of natural waters.
Use of CFCs as oceanic transient tracers is difficult for recently ventilated water masses as...