Articles | Volume 15, issue 4
https://doi.org/10.5194/os-15-1071-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/os-15-1071-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Aug 2019
Research article |
| 14 Aug 2019
| 14 Aug 2019
The influence of dissolved organic matter on the marine production of carbonyl sulfide (OCS) and carbon disulfide (CS2) in the Peruvian upwelling
Sinikka T. Lennartz
CORRESPONDING AUTHOR
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, Düsternbrooker
Weg 20, 24105 Kiel, Germany
now at: Institute for Chemistry and Biology of the Marine Environment, University of Oldenburg, Oldenburg, Germany
Marc von Hobe
Forschungszentrum Jülich GmbH, Institute of Energy and Climate
Research (IEK-7), Wilhelm-Johnen-Strasse, 52425 Jülich, Germany
Dennis Booge
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, Düsternbrooker
Weg 20, 24105 Kiel, Germany
Henry C. Bittig
Leibniz Institute for Baltic Sea Research Warnemünde,
Department of Physical Oceanography and Instrumentation, Seestraße 15, 18119 Rostock, Germany
Tim Fischer
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, Düsternbrooker
Weg 20, 24105 Kiel, Germany
Rafael Gonçalves-Araujo
Aarhus University, Department of Bioscience, Frederiksborgvej 399,
4000 Roskilde, Denmark
Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research, Department of Climate Sciences, Physical Oceanography of the Polar Seas, Klußmannstr. 3d, 27570 Bremerhaven, Germany
Kerstin B. Ksionzek
Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research, Department of Biosciences, Ecological Chemistry, Am Handelshafen 12, 27570 Bremerhaven, Germany
MARUM Center for Marine Environmental Sciences, Biogeochemistry, Leobener Straße,
28359 Bremen, Germany
Boris P. Koch
Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research, Department of Biosciences, Ecological Chemistry, Am Handelshafen 12, 27570 Bremerhaven, Germany
MARUM Center for Marine Environmental Sciences, Biogeochemistry, Leobener Straße,
28359 Bremen, Germany
University of Applied Sciences, An der Karlstadt, 27568 Bremerhaven, Germany
Astrid Bracher
Institute of Environmental Physics, University of Bremen, 28334
Bremen, Germany
Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research, Department of Climate Sciences, Physical Oceanography of the Polar Seas, Klußmannstr. 3d, 27570 Bremerhaven, Germany
Rüdiger Röttgers
Helmholtz-Zentrum Geesthacht, 21502 Geesthacht, Germany
Birgit Quack
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, Düsternbrooker
Weg 20, 24105 Kiel, Germany
Christa A. Marandino
GEOMAR Helmholtz Centre for Ocean Research Kiel, Marine Biogeochemistry, Düsternbrooker
Weg 20, 24105 Kiel, Germany
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Cited
22 citations as recorded by crossref.
- Biogeochemical controls on climatically active gases and atmospheric sulfate aerosols in the western Pacific F. Xu et al. 10.1016/j.envres.2023.115211
- Influence of dissolved organic matter on carbonyl sulfide and carbon disulfide formation from dimethyl sulfide during sunlight photolysis M. Modiri Gharehveran & A. Shah 10.1002/wer.1650
- Revealing the Marine Cycles of Volatile Sulfur Compounds and Their Biogeochemical Controls: A Case of the Western North Pacific F. Xu et al. 10.1021/acs.est.3c07498
- Tropospheric carbonyl sulfide mass balance based on direct measurements of sulfur isotopes C. Davidson et al. 10.1073/pnas.2020060118
- Remotely Sensed Carbonyl Sulfide Constrains Model Estimates of Amazon Primary Productivity J. Stinecipher et al. 10.1029/2021GL096802
- Carbonyl Sulfide Sulfur Isotope Fractionation During Uptake by C3 and C4 Plants C. Davidson et al. 10.1029/2022JG007035
- Rapid cycling and emission of volatile sulfur compounds in the eastern Indian Ocean: Impact of runoff inputs and implications for balancing atmospheric carbonyl sulfide budget F. Xu et al. 10.1016/j.watres.2024.122475
- Carbonyl sulfide measurements from a South Pole ice core and implications for atmospheric variability since the last glacial period M. Aydin et al. 10.5194/cp-20-1885-2024
- Influence of dissolved organic matter on carbonyl sulfide and carbon disulfide formation from cysteine during sunlight photolysis M. Modiri Gharehveran et al. 10.1039/D0EM00219D
- Lipid remodeling in phytoplankton exposed to multi-environmental drivers in a mesocosm experiment S. Cantarero et al. 10.5194/bg-21-3927-2024
- The response of aquatic ecosystems to the interactive effects of stratospheric ozone depletion, UV radiation, and climate change P. Neale et al. 10.1007/s43630-023-00370-z
- Photosensitized formation of sulfate and volatile sulfur gases from dissolved organic sulfur: Roles of pH, dissolved oxygen, and salinity J. Li et al. 10.1016/j.scitotenv.2021.147449
- The impacts of ocean acidification on marine trace gases and the implications for atmospheric chemistry and climate F. Hopkins et al. 10.1098/rspa.2019.0769
- Sulfur isotopic fractionation during hydrolysis of carbonyl sulfide Y. Avidani et al. 10.1016/j.marchem.2024.104458
- Intercomparison of Atmospheric Carbonyl Sulfide (TransCom‐COS): 2. Evaluation of Optimized Fluxes Using Ground‐Based and Aircraft Observations J. Ma et al. 10.1029/2023JD039198
- Inverse modelling of carbonyl sulfide: implementation, evaluation and implications for the global budget J. Ma et al. 10.5194/acp-21-3507-2021
- Biomass Burning Unlikely to Account for Missing Source of Carbonyl Sulfide J. Stinecipher et al. 10.1029/2019GL085567
- Plant gross primary production, plant respiration and carbonyl sulfide emissions over the globe inferred by atmospheric inverse modelling M. Remaud et al. 10.5194/acp-22-2525-2022
- Comparative assessment of machine learning algorithms for retrieving colored dissolved organic matter (CDOM) from Sentinel-2/MSI images in the coastal waters of the Persian Gulf B. Ahmadi et al. 10.1016/j.ecoinf.2025.103171
- Monthly resolved modelled oceanic emissions of carbonyl sulphide and carbon disulphide for the period 2000–2019 S. Lennartz et al. 10.5194/essd-13-2095-2021
- Characterization and identification of organic molecules in thermal desalination plant scale T. Green et al. 10.5004/dwt.2020.26334
- Evaluation of carbonyl sulfide biosphere exchange in the Simple Biosphere Model (SiB4) L. Kooijmans et al. 10.5194/bg-18-6547-2021
22 citations as recorded by crossref.
- Biogeochemical controls on climatically active gases and atmospheric sulfate aerosols in the western Pacific F. Xu et al. 10.1016/j.envres.2023.115211
- Influence of dissolved organic matter on carbonyl sulfide and carbon disulfide formation from dimethyl sulfide during sunlight photolysis M. Modiri Gharehveran & A. Shah 10.1002/wer.1650
- Revealing the Marine Cycles of Volatile Sulfur Compounds and Their Biogeochemical Controls: A Case of the Western North Pacific F. Xu et al. 10.1021/acs.est.3c07498
- Tropospheric carbonyl sulfide mass balance based on direct measurements of sulfur isotopes C. Davidson et al. 10.1073/pnas.2020060118
- Remotely Sensed Carbonyl Sulfide Constrains Model Estimates of Amazon Primary Productivity J. Stinecipher et al. 10.1029/2021GL096802
- Carbonyl Sulfide Sulfur Isotope Fractionation During Uptake by C3 and C4 Plants C. Davidson et al. 10.1029/2022JG007035
- Rapid cycling and emission of volatile sulfur compounds in the eastern Indian Ocean: Impact of runoff inputs and implications for balancing atmospheric carbonyl sulfide budget F. Xu et al. 10.1016/j.watres.2024.122475
- Carbonyl sulfide measurements from a South Pole ice core and implications for atmospheric variability since the last glacial period M. Aydin et al. 10.5194/cp-20-1885-2024
- Influence of dissolved organic matter on carbonyl sulfide and carbon disulfide formation from cysteine during sunlight photolysis M. Modiri Gharehveran et al. 10.1039/D0EM00219D
- Lipid remodeling in phytoplankton exposed to multi-environmental drivers in a mesocosm experiment S. Cantarero et al. 10.5194/bg-21-3927-2024
- The response of aquatic ecosystems to the interactive effects of stratospheric ozone depletion, UV radiation, and climate change P. Neale et al. 10.1007/s43630-023-00370-z
- Photosensitized formation of sulfate and volatile sulfur gases from dissolved organic sulfur: Roles of pH, dissolved oxygen, and salinity J. Li et al. 10.1016/j.scitotenv.2021.147449
- The impacts of ocean acidification on marine trace gases and the implications for atmospheric chemistry and climate F. Hopkins et al. 10.1098/rspa.2019.0769
- Sulfur isotopic fractionation during hydrolysis of carbonyl sulfide Y. Avidani et al. 10.1016/j.marchem.2024.104458
- Intercomparison of Atmospheric Carbonyl Sulfide (TransCom‐COS): 2. Evaluation of Optimized Fluxes Using Ground‐Based and Aircraft Observations J. Ma et al. 10.1029/2023JD039198
- Inverse modelling of carbonyl sulfide: implementation, evaluation and implications for the global budget J. Ma et al. 10.5194/acp-21-3507-2021
- Biomass Burning Unlikely to Account for Missing Source of Carbonyl Sulfide J. Stinecipher et al. 10.1029/2019GL085567
- Plant gross primary production, plant respiration and carbonyl sulfide emissions over the globe inferred by atmospheric inverse modelling M. Remaud et al. 10.5194/acp-22-2525-2022
- Comparative assessment of machine learning algorithms for retrieving colored dissolved organic matter (CDOM) from Sentinel-2/MSI images in the coastal waters of the Persian Gulf B. Ahmadi et al. 10.1016/j.ecoinf.2025.103171
- Monthly resolved modelled oceanic emissions of carbonyl sulphide and carbon disulphide for the period 2000–2019 S. Lennartz et al. 10.5194/essd-13-2095-2021
- Characterization and identification of organic molecules in thermal desalination plant scale T. Green et al. 10.5004/dwt.2020.26334
- Evaluation of carbonyl sulfide biosphere exchange in the Simple Biosphere Model (SiB4) L. Kooijmans et al. 10.5194/bg-18-6547-2021
Discussed (preprint)
Latest update: 06 May 2025
Short summary
The ocean emits the gases carbonyl sulfide (OCS) and carbon disulfide (CS2), which affect our climate. The goal of this study was to quantify the rates at which both gases are produced in the eastern tropical South Pacific (ETSP), one of the most productive oceanic regions worldwide. Both gases are produced by reactions triggered by sunlight, but we found that the amount produced depends on different factors. Our results improve numerical models to predict oceanic concentrations of both gases.
The ocean emits the gases carbonyl sulfide (OCS) and carbon disulfide (CS2), which affect our...
