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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">OS</journal-id>
<journal-title-group>
<journal-title>Ocean Science</journal-title>
<abbrev-journal-title abbrev-type="publisher">OS</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Ocean Sci.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1812-0792</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/os-10-17-2014</article-id>
<title-group>
<article-title>A parameter model of gas exchange for the seasonal sea ice zone</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Loose</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>McGillis</surname>
<given-names>W. R.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Perovich</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zappa</surname>
<given-names>C. J.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schlosser</surname>
<given-names>P.</given-names>
<ext-link>https://orcid.org/0000-0002-6514-4203</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Graduate School of Oceanography, University of Rhode Island, 215 South Ferry Rd., Narragansett, RI, 02882, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9W, Palisades, NY 10964, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>US Army Corps of Engineers Cold Regions Research and Engineering Laboratory, 72 Lyme Rd., Hanover, NH, 03755, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Earth and Environmental Sciences, Columbia University, Room 106 Geoscience Bldg., Palisades, NY 10964, USA</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Department of Earth and Environmental Engineering, Columbia University, 918 Seeley Mudd Bldg., Columbia University, 500 West 120th St, New York, NY 10027, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>28</day>
<month>01</month>
<year>2014</year>
</pub-date>
<volume>10</volume>
<issue>1</issue>
<fpage>17</fpage>
<lpage>28</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2014 B. Loose et al.</copyright-statement>
<copyright-year>2014</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://os.copernicus.org/articles/10/17/2014/os-10-17-2014.html">This article is available from https://os.copernicus.org/articles/10/17/2014/os-10-17-2014.html</self-uri>
<self-uri xlink:href="https://os.copernicus.org/articles/10/17/2014/os-10-17-2014.pdf">The full text article is available as a PDF file from https://os.copernicus.org/articles/10/17/2014/os-10-17-2014.pdf</self-uri>
<abstract>
<p>Carbon budgets for the polar oceans require better constraint on air–sea gas
exchange in the sea ice zone (SIZ). Here, we utilize advances in the theory
of turbulence, mixing and air–sea flux in the ice–ocean boundary layer (IOBL)
to formulate a simple model for gas exchange when the surface ocean is
partially covered by sea ice. The gas transfer velocity (&lt;i&gt;k&lt;/i&gt;) is related to
shear-driven and convection-driven turbulence in the aqueous mass boundary
layer, and to the mean-squared wave slope at the air–sea interface. We use
the model to estimate &lt;i&gt;k&lt;/i&gt; along the drift track of ice-tethered profilers
(ITPs) in the Arctic. Individual estimates of daily-averaged &lt;i&gt;k&lt;/i&gt; from ITP
drifts ranged between 1.1 and 22 m d&lt;sup&gt;−1&lt;/sup&gt;, and the fraction of open water
(&lt;i&gt;f&lt;/i&gt;) ranged from 0 to 0.83. Converted to area-weighted effective transfer
velocities (&lt;i&gt;k&lt;/i&gt;&lt;sub&gt;eff&lt;/sub&gt;), the minimum value of &lt;i&gt;k&lt;/i&gt;&lt;sub&gt;eff&lt;/sub&gt; was
10&lt;sup&gt;&amp;minus;5&lt;/sup&gt;5 m d&lt;sup&gt;−1&lt;/sup&gt; near &lt;i&gt;f&lt;/i&gt; = 0 with values exceeding &lt;i&gt;k&lt;/i&gt;&lt;sub&gt;eff&lt;/sub&gt;
 = 5 m d&lt;sup&gt;−1&lt;/sup&gt; at &lt;i&gt;f&lt;/i&gt; = 0.4. The model indicates that effects from
shear and convection in the sea ice zone contribute an additional 40% to
the magnitude of &lt;i&gt;k&lt;/i&gt;&lt;sub&gt;eff&lt;/sub&gt;, beyond what would be predicted from an
estimate of &lt;i&gt;k&lt;/i&gt;&lt;sub&gt;eff&lt;/sub&gt; based solely upon a wind speed parameterization.
Although the ultimate scaling relationship for gas exchange in the sea ice
zone will require validation in laboratory and field studies, the basic
parameter model described here demonstrates that it is feasible to formulate
estimates of &lt;i&gt;k&lt;/i&gt; based upon properties of the IOBL using data sources that
presently exist.</p>
</abstract>
<counts><page-count count="12"/></counts>
</article-meta>
</front>
<body/>
<back>
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